a, \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)

c, Ta có: \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)

Theo PT: \(n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)

PT: \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)

Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,4\left(mol\right)\)

Mà: H = 80%

\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=\dfrac{0,4}{80\%}=0,5\left(mol\right)\)

\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,5.46=23\left(g\right)\)

\(\Rightarrow V_{C_2H_5OH}=\dfrac{23}{0,8}=28,75\left(ml\right)\)

\(\Rightarrow V_{C_2H_5OH\left(18,4^o\right)}=\dfrac{28,75}{18,4}.100=156,25\left(ml\right)=0,15625\left(l\right)\)

\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_S=\dfrac{9,6}{32}=0,3\left(mol\right)\)

PTHH: \(Fe+S-^{t^o}\rightarrow FeS\)

Theo đề: 0,2...0,3

Lập tỉ lệ \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\)=> Fe hết. S dư

=> Sau phản ứng hỗn hợp gồm S dư, FeS

=> \(n_{S\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\)

S + H2SO4 → SO2 + H2O

2FeS + 10H2SO4 → Fe2(SO4)3 + 9SO2 + 10H2O

\(\Rightarrow m_{H_2SO_4}=\left(0,1+\dfrac{0,2.10}{2}\right).98=107,8\left(g\right)\)

\(V_{SO_2}=\left(0,1+\dfrac{0,2.9}{2}\right).22,4=22,4\left(l\right)\)

\(n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{FeS}=0,1\left(mol\right)\)

3Ba(OH)2 + Fe2(SO4)3 → 2Fe(OH)3↓ + 3BaSO4↓ (*)

Theo PT (*) : \(n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,05\left(mol\right)\)

Theo PT (**): \(n_{Fe_2O_3}=2n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)

\(\Rightarrow m_{Fe_2O_3}=0,1.160=16\left(g\right)\)

\(n_{CaCO_3}=\dfrac{150}{100}=1.5\left(mol\right)\)

\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)

\(n_{CaCl_2}=n_{CO_2}=n_{CaCO_3}=1.5\left(mol\right)\)

\(V_{CO_2}=1.5\cdot22.4=33.6\left(l\right)\)

\(C_{M_{CaCl_2}}=\dfrac{1.5}{0.5}=3\left(M\right)\)

Câu 1:

a. PTHH: MgCl₂ + HCl ---x--->

CaCO₃ + 2HCl ---> CO₂↑ + H₂O + CaCl₂ (1)

b. Ta có: \(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT₍₁₎: \(n_{HCl}=2.n_{CO_2}=2.0,3=0,6\left(mol\right)\)

Đổi 400ml = 0,4 lít

=> \(C_{M_{HCl}}=\dfrac{0,6}{0,4}=1,5M\)

c. PTHH: HCl + NaOH ---> NaCl + H₂O (2)

Vậy chất tác dụng với nước bắp cải tím là NaCl (muối ăn.)

Vậy dung dịch sau phản ứng làm nước bắp cải tím thành màu xam lam đậm.

Câu 2:

a. PTHH: CuO + H₂SO₄ ---> CuSO₄ + H₂O

b. Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)

Ta lại có: \(C_{\%_{H_2SO_4}}=\dfrac{m_{H_2SO_4}}{100}.100\%=19,6\%\)

=> \(m_{H_2SO_4}=19,6\left(g\right)\)

=> \(n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)

Ta thấy: \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\)

Vậy H₂SO₄ dư.

Theo PT: \(n_{CuSO_4}=n_{CuO}=0,1\left(mol\right)\)

=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)

Ta có: \(m_{dd_{CuSO_4}}=8+100=108\left(g\right)\)

=> \(C_{\%_{CuSO_4}}=\dfrac{16}{108}.100\%=14,81\%\)

a) \(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: CaCO₃ + 2HCl ---> CaCl₂ + CO₂ + H₂O

             0,3<-----0,6<------------------0,3

=> m = 0,3.100 = 30 (g)

b) \(C\%_{HCl}=\dfrac{0,6.36,5}{150}.100\%=14,6\%\)